90580-55-5Relevant academic research and scientific papers
Biomimetic Total Synthesis of Dysoxylum Alkaloids
Puerto Galvis, Carlos E.,Kouznetsov, Vladimir V.
, p. 15294 - 15308 (2019/11/29)
A five-step total synthesis of Dysoxylum alkaloids has been achieved using a biomimetic approach from zanthoxylamide protoalkaloids. The synthesis featured a direct amidation and a Bischler-Napieralski reaction to form the dihydroisoquinoline ring, which
Asymmetric hydrogenation of cyclic imines with an ionic Cp*Rh(III) catalyst
Li, Chaoqun,Xiao, Jianliang
supporting information; experimental part, p. 13208 - 13209 (2009/02/06)
When associated with a noncoordinating bulky counteranion, a cationic Cp*Rh(III)-diamine catalyst displayed excellent enantioselectivities in asymmetric hydrogenation of cyclic imines, affording bioactive tetrahydroisoquinolines and tetrahydro-β-carboline
Asymmetric synthesis of (s)-norlaudanosine and (s)-tetrahydrohomopapaverine by catalytic asymmetric hydrogenation with chiral diphosphine-iridium(i)-phthalimide complex catalysts
Morimoto, Toshiaki,Suzuki, Naoaki,Achiwa, Kazuo
, p. 2557 - 2560 (2007/10/03)
Optically active 1,2,3,4-tetrahydroisoquinoline alkaloids, (S)-norlaudanosine and (S)-tetrahydrohomopapaverine, were prepared by catalytic asymmetric hydrogenation of 1-substituted 3,4-dihydro-6,7-dimethoxyisoquinolines with 1 mol % of an iridium(I) compl
