905844-65-7

Basic information

• Product Name: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(azido)2]
• CAS NO: 905844-65-7
• Molecular Weight: 744.851
• Mol File: 905844-65-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(azido)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(azido)2](905844-65-7)
• EPA Substance Registry System: [Pd(1,1'-bis(diphenylphosphino)ferrocene)(azido)2](905844-65-7)

Safety Data

• Hazardous Substances Data: 905844-65-7(Hazardous Substances Data)

Upstream product

• 72287-26-4 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 

Downstream Products

• 905844-66-8 [Pd(1,1'-bis(diphenylphosphino)ferrocene)(N₄C-tert-Bu)2] 

Relevant articles and documents

Bis(azido) compounds of Pd and Pt with bulky phosphine ligands (dppn=1,8-bis(diphenylphosphino)naphthalene, dppf=1,1′-bis(diphenylphosphino)ferrocene, 1-dpn=1-diphenylphosphino-naphthalene): Preparation, structures, and reactivity toward isocyanides

Pd-bis(azido) compounds [Pd(dppn)(N3)2] and [Pd(dppf)(N3)2], which contain bulky chelating bis(phosphine) ligands (dppn=1,8-bis(diphenylphosphino)naphthalene, dppf=1,1′-bis(diphenylphosphino)ferrocene), were prepared from the corresponding chlorides and NaN3. We also prepared the Pt-bis(azido) compound [Pt(1-dpn)(SMe2)(N3)2] containing a bulky monodentate phosphine (1-dpn=1-diphenylphosphino-naphthalene). All these compounds underwent [2+3] cycloaddition with isocyanides (R-NC, R=cyclohexyl, tert-butyl, 2,6-dimethylphenyl) to convert azido ligands to five-membered, C-coordinated tetrazolate rings. In addition, we observed the [Pd(dppn)Cl2]-mediated C-C coupling of PhC{triple bond, short}CH to generate the η2-PhC{triple bond, short}C-C{triple bond, short}CPh ligand. All compounds have been structurally characterized by X-ray diffraction.