90587-89-6Relevant academic research and scientific papers
X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 19. INTRAMOLECULAR CYCLOADDITIONS OF NON-STABILISED AZOMETHINE YLIDES GENERATED VIA THE DECARBOXYLATIVE ROUTE FROM α-AMINO ACIDS.
Ardill, Harriet,Grigg, Ronald,Sridharan, Visuvanathar,Surendrakumar, Sivagnanasundram
, p. 4953 - 4966 (2007/10/02)
Heating a range of acyclic and cyclic secondary α-amino acids with aryl aldehydes containing a proximate terminal alkene or alkyne results in consecutive condensation and decarboxylation, followed by intramolecular cycloaddition of the resultant non-stabi
Decarboxylative Transamination. Mechanism and Applications to the Synthesis of Heterocyclic Compounds
Grigg, Ronald,Thianpatanagul, Sunit
, p. 180 - 181 (2007/10/02)
The currently accepted mechanism for decarboxylative transamination is shown to be incorrect; the intervention of 1,3-dipolar species in the decarboxylative transamination of α-amino acids is demonstrated by trapping with a range of dipolarophiles.
