90591-13-2

Basic information

• Product Name: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)]
• Synonyms: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)]
• CAS NO: 90591-13-2
• Molecular Weight: 790.198
• Mol File: 90591-13-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)](CAS DataBase Reference)
• NIST Chemistry Reference: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)](90591-13-2)
• EPA Substance Registry System: di-μ-bromo-bis[bromo(η(6)-para-cymene)ruthenium(II)](90591-13-2)

Safety Data

• Hazardous Substances Data: 90591-13-2(Hazardous Substances Data)

Upstream product

• 143-66-8 sodium tetraphenyl borate 
• 133271-73-5 (η6-cymene)(η3-tris(o-hydroxyphenyl)phosphine oxido-O,O',O'') ruthenium(II) 

Downstream Products

• 130004-34-1 {RuBr(p-cymene)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}Br 

Relevant articles and documents

STRUCTURAL CHARACTERISATION OF HYDROXO-BRIDGED ARENE-RUTHENIUM AND -OSMIUM COMPLEXES: FURTHER REACTIONS OF HYDROXO-BRIDGED COMPLEXES

Reaction of 2> with an excess of either aqueous NaOH or Na2CO3 followed by addition of Na gave two products, previously formulated as BPh4 (II) and BPh4*Me2CO (M = Ru (III), Os (IV)).X-ray structural analyses now reveal that the latter should be reformulated as the novel 2-OH)4(μ4-O)>(BPh4)2*2Me2CO tetramers containing a tetrahedrally coordinated O2- ion.In contrast, with substituted arenes the binuclear triple hydroxo-bridged cations of type III are formed asevidenced by the X-ray crystal structure determination of Cl*3H2O (V).Reactions of these various hydroxo-bridged complexes with HX (X = Cl, Br, I) gives either + and/or 2> whereas with CF3CO2H in the presence of arene', the dications 2+ are formed.