905931-87-5

Basic information

• Product Name: [1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride
• Synonyms: [1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride
• CAS NO: 905931-87-5
• Molecular Weight: 493.947
• Mol File: 905931-87-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: [1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride(905931-87-5)
• EPA Substance Registry System: [1,3-bis(2,6-diisopropylphenyl)-4,5-dichloro]imidazolium chloride(905931-87-5)

Safety Data

• Hazardous Substances Data: 905931-87-5(Hazardous Substances Data)

Upstream product

• 74663-75-5 1,2-bis(2,6-diisopropylphenylimino)ethane 
• 244187-81-3 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene 
• 250285-32-6 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride 

Downstream Products

• 1616704-01-8 [Se(1,3-bis(2,6-diisopropylphenyl)-4,5-dichloroimidazol-2-ylidene)] 

Relevant articles and documents

New expanded-ring NHC platinum(0) complexes: Synthesis, structure and highly efficient diboration of terminal alkenes

The synthesis and structural characterization of a series of novel platinum(0) complexes were reported. A number of (NHC)Pt(dvtms) (dvtms = 1,3-divinyl-1,1,3,3-tetramethyldisiloxane) complexes were investigated in catalytic addition of B2Pin2 to terminal alkenes. The novel expanded ring N-heterocyclic carbene complex (7-Dipp)Pt(dvtms) showed highest performance, turnover numbers up to 3800 were achieved. The scope of the reaction was illustrated by 20 examples with a variety of alkyl, alkoxy, halogen, ester, ketone and acetal substituents.

Pd-PEPPSI-IPentCl: A highly effective catalyst for the selective cross-coupling of secondary organozinc reagents

No migration? No problem! A series of new N-heterocyclic carbene based Pd complexes has been created and evaluated in the Negishi cross-coupling of aryl and heteroaryl chlorides, bromides, and triflates with a variety of secondary alkylzinc reagents (see scheme). The direct elimination product is nearly exclusively formed; in most examples there is no migratory insertion at all. Copyright