905981-22-8

Upstream product

• 75857-94-2 (5S)-N-(benzyloxycarbonyl)-5-methoxycarbonyl-2-pyrrolidinone 
• 93271-97-7 1-benzyloxycarbonyl-5-hydroxy-2-methoxycarbonylpyrrolidine 
• 93271-97-7 1-benzyl 2-methyl (2S)-5-hydroxypyrrolidine-1,2-dicarboxylate 
• 848467-50-5 2-benzyloxycarbonylamino-3-[6-(toluene-4-sulfonyloxy)-1H-indol-3-yl]-propionic acid methyl ester 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 863132-98-3 3-{2-benzyloxycarbonylamino-3-[2-methoxycarbonyl-2-(2-methoxycarbonyl-ethyl)-pyrrolidin-1-yl]-3-oxo-propyl}-7,7-dimethyl-7H-pyrano[2,3-g]indole-1-carboxylic acid tert-butyl ester 
• 848467-51-6 3-(2-benzyloxycarbonylamino-2-methoxycarbonyl-ethyl)-6-(1,1-dimethyl-prop-2-ynyloxy)-indole-1-carboxylic acid tert-butyl ester 
• 848467-53-8 3-(2-benzyloxycarbonylamino-2-carboxy-ethyl)-7,7-dimethyl-7H-pyrano[2,3-g]indole-1-carboxylic acid tert-butyl ester 
• 905981-24-0 3-(2-benzyloxycarbonylamino-2-methoxycarbonyl-ethyl)-7,7-dimethyl-7H-pyrano[2,3-g]indole-1-carboxylic acid tert-butyl ester 
• 848467-52-7 2-benzyloxycarbonylamino-3-(7,7-dimethyl-1,7-dihydro-pyrano[2,3-g]indol-3-yl)-propionic acid methyl ester 

Relevant academic research and scientific papers

Enantioselective total synthesis of avrainvillamide and the stephacidins

In this article, full details regarding our total synthesis of avrainvillamide and the stephacidins are presented. After an introduction and summary of prior synthetic studies in this family of structurally complex anticancer natural products, the evoluti

Short, enantioselective total synthesis of stephacidin A

A concise route to the heptacyclic indole alkaloid stephacidin A (1) includes a simple method for the gram-scale synthesis of substituted tryptophans, a remarkable indole annulation, and the first enolate coupling of an amide to an ester. This synthesis s