905982-99-2Relevant academic research and scientific papers
Enantioselective Aza-Wacker-Type Cyclization Promoted by Pd-SPRIX Catalyst
Sen, Abhijit,Takenaka, Kazuhiro,Sasai, Hiroaki
supporting information, p. 6827 - 6831 (2018/11/02)
An enantioselective aza-Wacker-type reaction was developed. When alkenyl sulfonamide substrates were treated with the Pd-SPRIX catalyst in the presence of oxone as an oxidant, the olefin was attacked intramolecularly by the nitrogen nucleophile to constru
Development of a [3+3] approach to tetrahydropyridines and its application in indolizidine alkaloid synthesis
Pattenden, Lisa C.,Adams, Harry,Smith, Stephen A.,Harrity, Joseph P.A.
, p. 2951 - 2961 (2008/09/19)
A stepwise [3+3] annelation sequence is described that generates tetrahydropyridines from the corresponding aziridines. The scope of this process is described and its potential for the stereoselective synthesis of indolizidines is highlighted by the synth
A [3+3] annelation approach to tetrahydropyridines
Pattenden, Lisa C.,Wybrow, Robert A. J.,Smith, Stephen A.,Harrity, Joseph P. A.
, p. 3089 - 3091 (2007/10/03)
A stepwise [3+3] annelation sequence to tetrahydropyridines via addition of the Buchi Grignard to aziridines has been developed. These intermediates can be further functionalized with good regio- and stereocontrol and this methodology has been employed in
