90606-25-0Relevant articles and documents
One-Pot Synthesis of N-((Trimethylsilyl)methyl)imines and (Trimethylsilyl)methyl-Substituted Heterocumulenes from (Trimethylsilyl)methyl Azide
Tsuge, Otohiko,Kanemasa, Shuji,Matsuda, Koyo
, p. 2688 - 2691 (2007/10/02)
The reactions of ((trimethylsilyl)methyl)iminotriphenylphosphorane, prepared in situ from (trimethylsilyl)methyl azide and triphenylphosphine, with carbonyl compounds and with heterocumulenes such as carbon dioxide, carbon disulfide, isocyanates, isothiocyanates, and a ketene provide convenient one-pot syntheses of the corresponding N-((trimethylsilyl)methyl)imines and (trimethylsilyl)methyl-substituted heterocumulenes, which are versatile reagents for the synthesis of heterocyclic compounds.