906067-69-4

Basic information

• Product Name: C₄₉H₇₇N₃O₃₇
• Synonyms: C₄₉H₇₇N₃O₃₇
• CAS NO: 906067-69-4
• Molecular Weight: 1300.15
• Mol File: 906067-69-4.mol

Chemical Properties

• CAS DataBase Reference: C₄₉H₇₇N₃O₃₇(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₉H₇₇N₃O₃₇(906067-69-4)
• EPA Substance Registry System: C₄₉H₇₇N₃O₃₇(906067-69-4)

Safety Data

• Hazardous Substances Data: 906067-69-4(Hazardous Substances Data)

Relevant articles and documents

Efficient photosensitized splitting of the thymine dimer/oxetane unit on its modifying β-cyclodextrin by a binding electron donor

Two modified β-cyclodextrins (β-CDs) with a thymine dimer and a thymine oxetane adduct respectively, TD-CD and Ox-CD, have been prepared, and utilized to bind an electron-rich chromophore, indole or N,N-dimethylaniline (DMA), to form a supramolecular complex. We have examined the photosensitized splitting of the dimer/oxetane unit in TD-CD/Ox-CD by indole or DMA via an electron-transfer pathway, and observed high splitting efficiencies of the dimer/oxetane unit. On the basis of measurements of fluorescence spectra and splitting quantum yields, it is suggested that the splitting reaction occurs in a supramolecular complex by an inclusion interaction between the modified β-CDs and DMA or indole. The back electron transfer, which leads low splitting efficiencies for the covalently-linked chromophore-dimer/oxetane compounds, is suppressed in the non-covalently-bound complex, and the mechanism has been discussed. The Royal Society of Chemistry 2006.