906077-03-0Relevant academic research and scientific papers
Synthesis of tetrahydroxy perhydroaza-azulenes: Tandem Johnson-Claisen rearrangement of d-glucose-derived allylic alcohols
Markad, Shankar D.,Karanjule, Narayan S.,Sharma, Tarun,Sabharwal, Sushma G.,Puranik, Vedavati G.,Dhavale, Dilip D.
, p. 2549 - 2555 (2008/02/08)
The Johnson-Claisen rearrangement of d-glucose-derived allylic alcohols 5a,b afforded sugar-substituted γ,δ-unsaturated ester 6 in high yield. Conversion of the ester group to an azidomethyl group, epoxidation of the double bond and hydrogenation gave pyr
Polyhydroxylated homoazepanes and 1-deoxy-homonojirimycin analogues: Synthesis and glycosidase inhibition study
Markad, Shankar D.,Karanjule, Narayan S.,Sharma, Tarun,Sabharwal, Sushma G.,Dhavale, Dilip D.
, p. 3675 - 3680 (2008/10/09)
The Johnson-Claisen rearrangement of d-gluco and l-ido-derived allylic orthoesters afforded γ,δ-unsaturated ester that on ester reduction, epoxidation, regioselective oxirane opening by sodium azide and hydrogenation led to sugar amino alcohols - immediat
