906077-13-2Relevant academic research and scientific papers
Synthesis of tetrahydroxy perhydroaza-azulenes: Tandem Johnson-Claisen rearrangement of d-glucose-derived allylic alcohols
Markad, Shankar D.,Karanjule, Narayan S.,Sharma, Tarun,Sabharwal, Sushma G.,Puranik, Vedavati G.,Dhavale, Dilip D.
, p. 2549 - 2555 (2008/02/08)
The Johnson-Claisen rearrangement of d-glucose-derived allylic alcohols 5a,b afforded sugar-substituted γ,δ-unsaturated ester 6 in high yield. Conversion of the ester group to an azidomethyl group, epoxidation of the double bond and hydrogenation gave pyr
