90619-83-3Relevant academic research and scientific papers
Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4
Schoch, Timothy D.,Mondal, Mukulesh,Weaver, Jimmie D.
supporting information, p. 1588 - 1593 (2021/03/03)
Presented is an economical means of removing fluorine from various highly fluorinated arenes using NaBH4. The procedure was adapted for different classes of perfluoroarenes. A novel isomer of an emerging class of organic dyes based on the carbazole phthalonitrile motif was succinctly synthesized in two steps from tetrafluorophthalonitrile, demonstrating the utility of the hydrodefluorination procedure. Initial exploration of the dye shows it to be photoactive and capable of facilitating contrathermodynamic styrenoid E/Z isomerization.
ORTHO-DISUBSTITUTED F-BENZENES - V. INTRAMOLECULAR HETEROATOM-FACILITATED ORTHO-SUBSTITUTION OF F-BENZENE DERIVATIVES WITH OXAZOLINYL AND OXAZINYL GROUPS.
Inukai,Takuma,Toritani,Sonoda,Kobayashi
, p. 225 - 231 (2007/10/02)
The oxazinyl and oxazolinyl substituents on an F-benzene ring facilitated the substitution of fluorine ortho to the heterocyclic functional groups by carbon and nitrogen nucleophiles. Alkylmagnesium halides and alkyllithium compounds were employed as the
