906377-60-4Relevant academic research and scientific papers
Pummerer fragmentation vs. Pummerer rearrangement: A mechanistic analysis
Laleu, Benoit,MacHado, Marco Santarem,Lacour, Jerome
, p. 2786 - 2788 (2006)
Depending upon the nature of the substituent at the β-position of the sulfoxide moiety, a Pummerer reaction can be oriented "at will" towards Cα-H (rearrangement) or Cα-C β (fragmentation) bond cleavage. The Royal Society of Chemistry 2006.
