906424-63-3Relevant academic research and scientific papers
A Retro-Staudinger Cycloaddition: Mechanochemical Cycloelimination of a β-Lactam Mechanophore
Robb, Maxwell J.,Moore, Jeffrey S.
, p. 10946 - 10949 (2015)
Mechanical activation of a β-lactam mechanophore using ultrasound induces a formal [2 + 2] cycloelimination reaction producing ketene and imine functional groups - the reverse reaction of the Staudinger cycloaddition. This transformation is predicted by c
Synthesis of N,4-diaryl substituted β-lactams via Kinugasa cycloaddition/rearrangement reaction
Michalak, Micha?,Stodulski, MacIej,Stecko, Sebastian,Wo?nica, Magdalena,Staszewska-Krajewska, Olga,Kalicki, Przemys?aw,Furman, Bart?omiej,Frelek, Jadwiga,Chmielewski, Marek
, p. 10806 - 10817 (2013/01/15)
The methodology of construction of N,4-diaryl substituted β-lactam framework, based on the Kinugasa cycloaddition/rearrangement sequence is presented. The series of protected chiral propargyl alcohols was treated with diaryl nitrones to afford mainly the
