906478-61-3Relevant academic research and scientific papers
Magnetic field effects on the decay rates of triplet biradical photogenerated from intramolecular electron-transfer in a zinc- tetraphenylporphyrin-fullerene linked compound
Yonemura, Hiroaki,Nobukuni, Hideki,Moribe, Shinya,Yamada, Sunao,Fujiwara, Yoshihisa,Tanimoto, Yoshifumi
, p. 417 - 422 (2004)
Transient absorption spectra of a zinc-tetraphenylporphyrin(ZnP)- fullerene(C60) linked compound with flexible eight methylene groups indicated that intramolecular electron-transfer occurred in benzonitrile, while not in toluene. In benzonitrile, the decay rate constant of biradical decreases quickly in lower magnetic fields (60. The reverse phenomenon of the MFEs around 0.1 T is most likely ascribed to the properties of C60 moiety.
