906483-81-6

Basic information

• Product Name: (zirconium)2(hydrido)3(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)2(HB(C6F5)3)
• CAS NO: 906483-81-6
• Molecular Weight: 1227.29
• Mol File: 906483-81-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (zirconium)2(hydrido)3(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)2(HB(C6F5)3)(CAS DataBase Reference)
• NIST Chemistry Reference: (zirconium)2(hydrido)3(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)2(HB(C6F5)3)(906483-81-6)
• EPA Substance Registry System: (zirconium)2(hydrido)3(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)2(HB(C6F5)3)(906483-81-6)

Safety Data

• Hazardous Substances Data: 906483-81-6(Hazardous Substances Data)

Upstream product

• 785832-40-8 (zirconium)2(hydrido)4(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)2 
• 1109-15-5 tris(pentafluorophenyl)borate 

Downstream Products

• 906483-82-7 (zirconium)(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)(HB(C6F4)(C6F5) 
• 906483-83-8 (zirconium)(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl)HB(C6F5)3 
• 206071-53-6 (zirconium)(1,2-ethylene-1,1'-bis(η5-tetrahydroindenyl) difluoride 

Relevant articles and documents

Formation of zirconocene fluoro complexes: No deactivation in the polymerization of olefins by the contact-ion-pair catalysts [Cp′ 2ZrR]+[RB(C6F5)3] -

(Chemical Equation Presented) Not a catalyst killer: In the reaction of 2 with B(C6F5)3, a nucleophilic aromatic substitution with C-F bond cleavage leads to the unexpected difluoride 1. Although the formation of Zr-F species during olefin polymerization by [Cp′2ZrR]+[RB(C6F5) 3]- (Cp′ = substituted or unsubstituted η5-cyclopentadienyl; R = Me, H) catalysts is often described as a deactivation, the catalyst precursor 2 can be regenerated from 1 through treatment with iBu2AlH.