90652-44-1Relevant academic research and scientific papers
EVOLUTION THERMIQUE DE N-OXYDES DE DIMETHYLAMINO-5 ALCANOLS-1 SUBSTITUES EN 5. COMPETITION ENTRE REARRANGEMENTS DE COPE ET DE MEISENHEIMER
Barbry, Didier,Hasiak, Bruno,Augait, Jean-Michel,Couturier, Daniel
, p. 956 - 961 (2007/10/02)
The effect of the substituent R in the 5 position was studied in the decomposition of 1,5-aminoalcohol N-oxides: Meisenheimer rearrangements takes place when R is the vinyl group but is not observed with the phenyl substituent; elimination to alkenol only
Action d'organometalliques fonctionnels sur les gem-aminoethers et les sels d'immonium. III. Synthese d'amines tertiaires ο-fonctionnelles
Courtois, Gilles,Miginiac, Philippe
, p. 148 - 152 (2007/10/02)
The reaction of several ο-functionalised Grignard reagents /= 4> with immonium salts or with gem-aminoethers proceeds readily and in generally good yield to give tertiary amines of the type Y-(CH2)n-CH(R')-NR"2 (Y=Cl,OR,SR,NR2).Hydroxyl (Y
