90656-59-0Relevant academic research and scientific papers
Nitrosation of ketone dianions
Ikeda,Haraguchi,Yukawa,Niiya,Goto
, p. 526 - 528 (1995)
Nitrosation of α,α'-dianions produced from ketones using a couple of bases was carried out with tert-butyl nitrite(tert-BuONO) in ether, and then two regioisomers of oximes(but notacetone)were obtained simultaneously. The ratio of these regioisomers was remarkably reversed by the addition of hexamethylphosphoric triamide (HMPA).
