90670-67-0Relevant articles and documents
Phosphorus azides, powerful reagents in heterocyclic chemistry
Majoral, Jean-Pierre,Bertrand, Guy,Ocando-Mavarez, Edgar,Baceiredo, Antoine
, p. 945 - 958 (2007/10/02)
The Curtius type rearrangement is effective for tetracoordinated and pentacoordinated phosphorus azides.Competitive nitrene-type reactions sometimes occur.On the other hand, irradionation of tricoordinated phosphorus azides lead to the generation of phosp
PHOSPHORUS-NITROGEN TRIPLE-BONDED SPECIES
Majoral, Jean-Pierre,Bertrand, Guy,Baceiredo, Antoine,Mavarez, Edgar Ocando
, p. 75 - 80 (2007/10/02)
Evidence for the transient formation of new phosphorus-nitrogen triple bonded species are given.Rules concerning the photolytic and thermolytic behavior of azides are reported.