906739-75-1

Upstream product

• 906739-15-9 methyl 2-diazo-2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)acetate 
• 530-48-3 1,1-Diphenylethylene 
• 73183-34-3 bis(pinacol)diborane 
• 454185-98-9 methyl [4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]acetate 
• 41841-16-1 (4-bromo-phenyl)-acetic acid methyl ester 

Relevant academic research and scientific papers

Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions

Rhodium(II)-catalyzed reactions of aryldiazoacetates can be conducted in the presence of iodide, triflate, organoboron, and organostannane functionality, resulting in the formation of a variety of cyclopropanes or C-H insertion products with high stereoselectivity. The combination of the rhodium(II)-catalyzed reaction with a subsequent palladium(II)-catalyzed Suzuki coupling offers a novel strategy for diversity synthesis.