906739-82-0Relevant articles and documents
Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions
Ni, Aiwu,France, Jessica E.,Davies, Huw M. L.
, p. 5594 - 5598 (2007/10/03)
Rhodium(II)-catalyzed reactions of aryldiazoacetates can be conducted in the presence of iodide, triflate, organoboron, and organostannane functionality, resulting in the formation of a variety of cyclopropanes or C-H insertion products with high stereoselectivity. The combination of the rhodium(II)-catalyzed reaction with a subsequent palladium(II)-catalyzed Suzuki coupling offers a novel strategy for diversity synthesis.