90675-35-7Relevant academic research and scientific papers
Reaction of Dichlorotriphenylphosphorane with Bis(trimethylsilyl) Peroxide. A new Method for the Formation of Electrophilic Chlorine Source.
Shibata, Kazusato,Itoh, Yukinori,Tokitoh, Norihiro,Okazaki, Renji,Inamoto, Naoki
, p. 3749 - 3751 (2007/10/02)
Reactions of dichlorotriphenylphosphorane with bis(trimethylsilyl) peroxide in the presence of some organic compounds have been found to give chlorinated products.Aromatic hydrocarbons bearing electron-donating substituents give the corresponding monochloroarenes, while an enol silyl ether is converted into α-chloro-ketone.The mechanism is briefly discussed.
