90702-06-0

Basic information

• Product Name: Benzonitrile, 3-bromo-4-[[(2,5-dioxo-1-pyrrolidinyl)methyl]methylamino]-
• CAS NO: 90702-06-0
• Molecular Formula: C13H12BrN3O2
• Molecular Weight: 322.161
• Mol File: 90702-06-0.mol

Chemical Properties

• CAS DataBase Reference: Benzonitrile, 3-bromo-4-[[(2,5-dioxo-1-pyrrolidinyl)methyl]methylamino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzonitrile, 3-bromo-4-[[(2,5-dioxo-1-pyrrolidinyl)methyl]methylamino]-(90702-06-0)
• EPA Substance Registry System: Benzonitrile, 3-bromo-4-[[(2,5-dioxo-1-pyrrolidinyl)methyl]methylamino]-(90702-06-0)

Safety Data

• Hazardous Substances Data: 90702-06-0(Hazardous Substances Data)

Upstream product

• 128-08-5 N-Bromosuccinimide 
• 1197-19-9 4-cyano-N,N-dimethylaniline 

Relevant articles and documents

Catalyst and Additive-Free Direct Amidation/Halogenation of Tertiary Arylamines with N-haloimide/amides

An approach has been developed for the amidation (halogenation) of tertiary arylamines by electrophilic activation using N-haloimide/amides. Several control experiments have been performed, and the coupling reaction outcomes indicated that the N-haloimide/amide brings three major functions, including electrophilic activation, aromatic halogenation and nucleophilic nitrogen sources. This cascade reaction features simple manipulation, requires no additional catalyst, oxidant or additives, and is performed under mild conditions. (Figure presented.).

Succinimidation by N-Bromosuccinimide of N,N-Dimethylamido and N,N-Dimethylamino Groups

N,N-Dimethylamides (1)-(6) and N,N-dimethylamines (7)-(10) are converted by the action of N-bromosuccinimide (NBS) in carbon tetrachloride and in the presence of a catalytic amount of benzoyl peroxide into the corresponding succinimido derivatives (11)-(2