90729-76-3

Upstream product

• 344411-26-3 (5-[1,3]Dioxolan-2-yl-3-methyl-1-phenethyl-penta-1,2-dienyloxy)-trimethyl-silane 
• 343815-20-3 7-[1,3]Dioxolan-2-yl-1-phenyl-3-trimethylsilanyl-hept-4-yn-3-ol 
• 61157-31-1 3-phenylpropionyltrimethylsilane 
• 74-88-4 methyl iodide 

Relevant academic research and scientific papers

SPECIFIC GENERATION OF LITHIATED 3-TRIMETHYLSILOXY-1,2-PROPADIENE DERIVATIVES FROM 1-(TRIMETHYLSILYL)PROPARGYL ALCOHOLS.

1-(Trimethylsilyl)propargyl alcohols have been prepared by treating acyltrimethylsilanes with magnesium acetylides, and their base-induced reactions involving rearrangement of silyl group have been examined. Treatment of the alcohol with an equimolar amou

BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL. GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS

Under the effect of butyllithium, 1-trimethylsilylpropagyl alcohol undergoes rearrangement to afford the corresponding trimethylsiloxyallene or its lithiated one, which can be used for the preparation of α,β-unsaturated ketone derivatives.