90737-25-0

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 795-43-7 bis(4-hydroxyphenyl)(phenyl)phosphine oxide 
• 106-89-8 epichlorohydrin 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 54300-32-2 di(4-fluorophenyl)-phenylphosphine oxide 
• 799-55-3 bis(4-methoxyphenyl)(phenyl)phosphine oxide 
• 14180-51-9 bis(4-methoxyphenyl)phenylphosphine 

Relevant academic research and scientific papers

PHENYLPHOSPHINE OXIDE AND OXYGEN STABLE EPOXY POLYMERS AND METHODS OF SYNTHESIS

A polymer formed of at least one phenylphosphine oxide functional epoxide crosslinked with at least one phenylphosphine oxide amine such that the polymer has phosphorous concentrations of at least about 8 percent by weight, at least about 8.5 percent by weight, or any value or range of values therebetween.

Synthesis method of carbonate modified fluoride-free organic phosphine ligand

The invention relates to the field of organic synthesis and provides a synthesis method of a carbonate modified fluoride-free organic phosphine ligand. The synthesis method comprises the following steps: preparing a Grignard reagent from the raw material p-bromoanisole or derivative thereof; enabling the Grignard reagent to react with a phosphorus source to generate a skeleton structure molecule with triphenylphosphine; and performing oxidation, demethylation, nucleophilic substitution and reduction to obtain a target molecular structure. The synthesis method has the following effects and benefits: a novel carbon dioxide-philic organic phosphine ligand is synthesized, the solubility of the phosphine ligand in supercritical CO2 is increased, and application of a fluoride-free phosphine ligand organic metal catalyst in supercritical CO2 is realized. Moreover, the organic carbonate compound is insoluble in a weakly (non-) polar organic solvent (such as alkane compounds), the property enables a phase splitting function of the carbonate modified fluoride-free organic phosphine ligand in the reaction system, and the recycling and reusing of the catalyst are realized.