90761-62-9

Basic information

• Product Name: (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE
• Synonyms: (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE;(S)-(+)-N-(3,5-DINITROBENZOYL)PHENYLGLYCINE;(S)-3,5-DINITRO-BENZOYL-L-PHENYL GLYCINE;N-(3,5-DINITROBENZOYL)-L-ALPHA-PHENYLGLYCINE;D-3,5-Dinitrobenzoylleucine;N-(3,5-DINITROBENZOYL)-S-(+)-A-PHENYLGLY CINE, 95%;N-(3 5-DINITROBENZOYL)-L-ALPHA-PHENYL- &;(S)-(+)-N-(3,5-DINITROBENZOYL) PHENYLGLYCINE 98+%
• CAS NO: 90761-62-9
• Molecular Formula: C₁₅H₁₁N₃O₇
• Molecular Weight: 345.26
• Mol File: 90761-62-9.mol
• Article Data: 6

Chemical Properties

• Melting Point: 218-220 °C(lit.)
• Boiling Point: 569.4 °C at 760 mmHg
• Flash Point: 298.2 °C
• Appearance: /
• Density: 1.527g/cm³
• Vapor Pressure: 8.34E-14mmHg at 25°C
• Refractive Index: 1.662
• PKA: 3.34±0.10(Predicted)
• BRN: 4719761
• CAS DataBase Reference: (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE(90761-62-9)
• EPA Substance Registry System: (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE(90761-62-9)

Safety Data

• Safety Statements: 22-24/25
• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 90761-62-9(Hazardous Substances Data)

Usage

General Description

"(S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE" is a compound that belongs to the family of organic compounds known as phenylglycines. This chemical is solid in state and comes in a white color. (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLGLYCINE has the molecular formula CHNO and its molecular weight is 360.23 g/mol. It contains a dinitrobenzoyl group, which is a strong electron-withdrawing group that contributes to its reactivity. The (S)-(+)-N-(3,5-dinitrobenzoyl)-alpha-phenylglycine, having multiple active sites in its structure, can play a pivotal role in numerous chemical reactions that makes it crucially important in chemical industries and laboratories.

InChI:InChI=1/C15H11N3O7/c19-14(16-13(15(20)21)9-4-2-1-3-5-9)10-6-11(17(22)23)8-12(7-10)18(24)25/h1-8,13H,(H,16,19)(H,20,21)/t13-/m0/s1

Upstream product

• 74958-71-7 (R)-(-)-N-(3,5-dinitrobenzoyl)-α-phenylglycine 
• 2835-06-5 phenylglycin 
• 99-33-2 3,5-dinitrobenoyl chloride 
• 611-73-4 Benzoylformic acid 
• 2935-35-5 (S)-2-phenylglycine 

Downstream Products

• 1309141-65-8 BDNP 
• 1309141-59-0 DDNP 
• 1309150-66-0 ammonium N-(3,5-dinitrobenzoyl)-α-phenylglycinate 
• 1309141-62-5 n-propylammonium N-(3,5-dinitrobenzoyl)-α-phenylglycinate 
• 1222074-03-4 (S)-(-)-2-(N-propylamino)-5-methoxytetraline (+)-N-(3,5-dinitrobenzoyl)-α-phenylglycine salt 
• 479623-46-6 2-[(S)-N-(3,5-dinitrobenzoyl)amino-phenylacetyl]-2-{[4-allylamino-6-(R)-(1-(1-naphthyl)ethylamino)-1,3,5-triazin-2-yl]oxy}ethylamine 

Relevant articles and documents

COMPOSITIONS AND METHODS FOR CYCLOFRUCTANS AS SEPARATION AGENTS

The present invention relates to derivatized cyclofructan compounds, compositions comprising derivatized cyclofructan compounds, and methods of using compositions comprising derivatized cyclofructan compounds for chromatographic separations of chemical species, including enantiomers. Said compositions may comprise a solid support and/or polymers comprising derivatized cyclofructan compounds.

Continuous separation of racemic 3,5-dinitrobenzoyl-amino acids in a centrifugal contact separator with the aid of cinchona-based chiral host compounds

The resolution of racemates is mostly performed by crystallisation of diastereomeric salts. Direct physical separation could be much more efficient, but so far most concepts, with the exception of SMB, have proven to be non-scaleable. Here we report the f

Enantioselective hydrolysis of N-acylated α-amino esters at a biphasic interface: Tandem reaction kinetic resolution using a chiral complexing agent

equation presented Highly enantioselective hydrolytic kinetic resolutions of esters derived from N-acylated α-amino acids proceed rapidly at hydrocarbon/water interfaces in the presence of a proline-derived chiral selector. When performed in tandem with an enantioselective biphasic esterification reaction, esters of 100% enantiomeric excess are obtained.