90772-55-7

Usage

InChI:InChI=1/C10H9BrO2/c1-4-7-5-9(12-2)10(13-3)6-8(7)11/h1,5-6H,2-3H3

Upstream product

• 61051-70-5 (2-bromo-4,5-dimethoxy-phenyl)-propiolic acid 
• 4114-28-7 diethyl hydrazodicarboxylate 
• 457885-42-6 1-bromo-2-[(Z)-2-bromoethenyl]-4,5-dimethoxybenzene 
• 5392-10-9 2-bromo-4,5-dimethoxybenzaldehyde 
• 90965-06-3 dimethyl 1-(1-diazo-2-oxopropyl)phosphonate 

Downstream Products

• 1337926-86-9 C₂₉H₃₆BrNO₅Si 
• 1337926-96-1 C₂₁H₂₂BrNO₅ 
• 1337926-87-0 C₂₁H₂₄BrNO₅ 
• 1805-85-2 (-)-hasubanonine 

Relevant academic research and scientific papers

Copper-catalyzed tandem C-N bond formation: An efficient annulative synthesis of functionalized cinnolines

Cinn-tillating synthesis: The combination of a readily available copper catalyst, a simple hydrazide nucleophile, and established difunctionalized building blocks provides a new, flexible route to an under-developed class of aromatic heterocycles, cinnolines (see scheme). Copyright

Efficient entry to the hasubanan alkaloids: First enantioselective total syntheses of (-)-hasubanonine, (-)-runanine, (-)-delavayine, and (+)-periglaucine B

Maximized divergence: The hasubanan alkaloids given in the scheme have been synthesized in eight or nine steps from the aryl azide 1. The utility of 5-trimethylsilylcyclopentadiene as an easily removed, stabilizing stereocontrol element has been demonstrated.