90789-72-3Relevant academic research and scientific papers
ORGANOBORON COMPOUNDS. CDVIII. REACTION OF 1-BORAADAMANTANE WITH AROMATIC NITRILES
Mikhailov, B. M.,Baryshnikova, T. K.
, p. 25 - 30 (2007/10/02)
1-Boraadamantane has been shown to react with benzonitrile, and with o- and p-methylbenzonitriles with the formation of 1/1 complexes, which are converted at 200 deg C into 5-substituted 3-bora-4-aza-1,1-bihomoadamant-4-enes which exist in the dimer form.
CHEMISTRY OF 1-BORAADAMANTANE.
Mikhailov
, p. 1439 - 1452 (2008/10/08)
1-Borraadamantane is a unique compound both in respect to its structure and chemical behavior. Methods for the synthesis of the 1-boraadamantane compounds and their reactions with carbonyl compounds, aromatic nitriles, nitrogenous and phosphorous ylides, as well as protolysis, halogenation, carbonylation, and amination of the 1-boraaadamantane derivatires, are described. An application of 1-boraadamantane to organic synthesis is considered, including the preparation of the adamantane, homoadamantane, and 1-azaadamantane compounds.
