90789-80-3Relevant academic research and scientific papers
ORGANOBORON COMPOUNDS. CDVII. REACTION OF 1-BORAADAMANTANE WITH PHOSPHORUS YLIDES: SYNTHESIS OF 4-ALKYL-3-BORAHOMOADAMANTANES
Gurskii, M. E.,Pershin, D. G.,Mikhailov, B. M.
, p. 17 - 24 (2007/10/02)
Alkylidenetriphenylphosphoranes react with the tetrahydrofuran complex of 1-boraadamantane to form stable adducts.The adducts rearrange to compounds of the 4-alkyl-3-borahomoadamantane series.
CHEMISTRY OF 1-BORAADAMANTANE.
Mikhailov
, p. 1439 - 1452 (2008/10/08)
1-Borraadamantane is a unique compound both in respect to its structure and chemical behavior. Methods for the synthesis of the 1-boraadamantane compounds and their reactions with carbonyl compounds, aromatic nitriles, nitrogenous and phosphorous ylides, as well as protolysis, halogenation, carbonylation, and amination of the 1-boraaadamantane derivatires, are described. An application of 1-boraadamantane to organic synthesis is considered, including the preparation of the adamantane, homoadamantane, and 1-azaadamantane compounds.
