907959-18-6Relevant articles and documents
Nickel-Catalyzed Reductive Cross-Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides: A One-Pot Synthesis of Diarylmethanes
Zhang, Jie,Lu, Gusheng,Xu, Jin,Sun, Hongmei,Shen, Qi
supporting information, p. 2860 - 2863 (2016/07/06)
The first nickel-catalyzed, magnesium-mediated reductive cross-coupling between benzyl chlorides and aryl chlorides or fluorides is reported. A variety of diarylmethanes can be prepared in good to excellent yields in a one-pot manner using easy-to-access mixed PPh3/NHC Ni(II) complexes of Ni(PPh3)(NHC)Br2 (NHC = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr, 1a; 1,3-di-tert-butylimidazol-2-ylidene, ItBu, 1b) as catalyst precursors. Activation of polychloroarenes or chemoselective cross-coupling based on the difference in catalytic activity between 1a and 1b is used to construct oligo-diarylmethane motifs.
Polycyanurate networks with enhanced segmental flexibility and outstanding thermochemical stability
Guenthner, Andrew J.,Davis, Matthew C.,Ford, Michael D.,Reams, Josiah T.,Groshens, Thomas J.,Baldwin, Lawrence C.,Lubin, Lisa M.,Mabry, Joseph M.
, p. 9707 - 9718 (2013/03/13)
The synthesis and physical properties of cyanurate networks formed from two new tricyanate monomers, 1,3,5-tris[(4-cyanatophenylmethyl]benzene and 3,5-bis[(4-cyanatophenylmethyl)]phenylcyanate, are reported and compared to those of 1,1,1-tris[(4-cyanatoph