908119-73-3Relevant academic research and scientific papers
Palladium-imidazolinium carbene-catalyzed arylation of aldehydes with arylboronic acids in water
Kuriyama, Masami,Ishiyama, Natsuki,Shimazawa, Rumiko,Onomura, Osamu
experimental part, p. 6814 - 6819 (2010/10/02)
The catalytic arylation of aldehydes with arylboronic acids in only water was found to be achieved using the palladium/thioether-imidazolinium chloride system in good to excellent yields. This catalytic process showed high tolerance for a broad range of substrates, giving a variety of carbinol derivatives with 2.0-3.0 mol % of the catalyst.
Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands
Kuriyama, Masami,Shimazawa, Rumiko,Enomoto, Terumichi,Shirai, Ryuichi
, p. 6939 - 6942 (2008/12/22)
(Chemical Equation Presented) Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether- imidazolinium carbene ligands proceeded readily under aqueous conditions. This process tolerated a diverse range of potassium trifluoroborate salts and aldehydes, giving a variety of carbinol derivatives with good to excellent yields.
