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η6-Benzenebis(trimethylphosphine)phenylrhenium is a complex organometallic compound with the chemical formula C21H30P2Re. It consists of a rhenium (Re) metal center, a phenyl group (C6H5), and two trimethylphosphine ligands (P(CH3)3). The η6 notation indicates that the benzene ring is coordinated to the rhenium center through all six of its carbon atoms, forming a cyclic structure. η6-benzenebis(trimethylphosphine)phenylrhenium is of interest in organometallic chemistry and catalysis due to its unique structure and potential applications in various chemical transformations. It is typically synthesized through the reaction of rhenium precursors with benzene and trimethylphosphine, and its properties, such as stability and reactivity, are influenced by the nature of the metal center and the ligands surrounding it.

90885-78-2

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90885-78-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 90885-78-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,0,8,8 and 5 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 90885-78:
(7*9)+(6*0)+(5*8)+(4*8)+(3*5)+(2*7)+(1*8)=172
172 % 10 = 2
So 90885-78-2 is a valid CAS Registry Number.

90885-78-2Downstream Products

90885-78-2Relevant academic research and scientific papers

Synthesis of Mono-η-benzenebis(trimethylphosphine)-manganese and -rhenium Compounds Using the Metal Atoms

Green, Malcolm L. H.,O'Hare, Dermot,Wallis, Julian M.

, p. 233 - 234 (2007/10/02)

Co-condensation of manganese or rhenium atoms with a mixture of benzene and trimethylphosphine forms the compounds Mn(η-C6H6)(PMe3)2H and 2 respectively; the latter gives rise to the derivatives Re(η-C6H6)(PMe3)2R (R = I or H).

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