909023-11-6

Basic information

• Product Name: (1S,2R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-phenyl)-1-nitro-propan-2-ol
• CAS NO: 909023-11-6
• Molecular Weight: 341.48
• Mol File: 909023-11-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-phenyl)-1-nitro-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-phenyl)-1-nitro-propan-2-ol(909023-11-6)
• EPA Substance Registry System: (1S,2R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-phenyl)-1-nitro-propan-2-ol(909023-11-6)

Safety Data

• Hazardous Substances Data: 909023-11-6(Hazardous Substances Data)

Upstream product

• 29559-26-0 (p-methoxyphenyl)nitromethane 
• 102191-92-4 tert-butyldimethylsiloxyacetaldehyde 

Downstream Products

• 237736-11-7 (-)-(4S,5R)-5-hydroxymethyl-4-(4-methoxyphenyl)-1,3-oxazolidin-2-one 
• 909023-12-7 (4S,5R)-5-(tert-Butyl-dimethyl-silanyloxymethyl)-4-(4-methoxy-phenyl)-oxazolidin-2-one 

Relevant articles and documents

Diastereoselective and enantioselective Henry (nitroaldol) reaction utilizing a guanidine-thiourea bifunctional organocatalyst

A highly enantio- and diastereoselective Henry reaction of various aldehydes with nitroethane was developed using the guanidine-thiourea bifunctional catalyst 1 (syn selectivity of 86:14 to 99:1 with 84-99% ee). A variety of nitroalkanes was treated with