909270-36-6

Basic information

• Product Name: (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one
• Synonyms: (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one
• CAS NO: 909270-36-6
• Molecular Weight: 420.689
• Mol File: 909270-36-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one(909270-36-6)
• EPA Substance Registry System: (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one(909270-36-6)

Safety Data

• Hazardous Substances Data: 909270-36-6(Hazardous Substances Data)

Upstream product

• 137688-20-1 (R)-2-(but-3-en-1-yl)oxirane 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 909270-39-9 (R)-tert-butyl-(1-iodomethyl-pent-4-enyloxy)-dimethylsilane 
• 184435-75-4 (5S)-5-methyl-3-phenylsulfanyl-4,5-dihydrofuran-2(3H)-one 

Downstream Products

• 909270-52-6 (2'R,5S,8'R,11'R,12'R,15'R,16'R)-3-[2'-(tert-butyldimethylsilanyloxy)-8',11',15'-(trimethoxymethoxy)-12',16'-oxidotriacontanyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one 
• 909270-50-4 (2'R,5S,8'S,11'R,12'R,15'R,16'R)-3-[2'-(tert-butyldimethylsilanyloxy)-8',11',15'-(trimethoxymethoxy)-12',16'-oxidotriacont-5'-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one 

Relevant articles and documents

Convergent synthesis of pyragonicin

This paper describes a second-generation synthesis of an antitumor tetrahydropyran (THP) acetogenin, pyragonicin. The key step involved an olefin cross-metathesis between the THP segment and the terminal γ-lactone residue. The coupling reaction in the pre