90933-92-9Relevant academic research and scientific papers
REACTIVITE DE SILANES PROPARGYLIQUES α-FONCTIONNELS VIS A VIS DES DERIVES CARBONYLES: PREPARATION D'ALCOOLS-ETHER, DE DIOLS ET DE DIOXANNES
Pornet, Jacques,Randrianoelina, Benjamin,Miginiac, Leone
, p. 651 - 654 (1984)
Type 1 functional propalgyltrimethylsilanes react with carbonyl derivatives, in the presence of titanium tetrachloride or tetra-n-butylammonium fluoride, to produce allenic alcohols-ethers, diols and dioxanes.
SYNTHESE D'HETEROCYCLES OXYGENES A GROUPE VINYLIDENE EXOCYCLIQUE PAR VOIE ORGANOSILICIQUE - PARTIE II*: PREPARATION DE VINYLIDENE-5 DIOXANNES-1,3
Pornet, J.,Damour, D.,Randrianoelina, B.,Miginiac, L.
, p. 2501 - 2510 (2007/10/02)
The α-silyloxypropargyltrimethylsilanes regiospecifically react with aliphatic aldehydes to lead to alkyl-substituted 5-vinylidene-1,3-dioxanes, in a one-pot reaction.
