90949-01-2Relevant academic research and scientific papers
Intramolecular schmidt reactions of azides with carbocations: Synthesis of bridged-bicyclic and fused-bicyclic tertiary amines
Pearson, William H.,Walavalkar, Rajesh,Schkeryantz, Jeffrey M.,Fang, Wen-Kui,Blickensdorf, James D.
, p. 10183 - 10194 (2007/10/02)
Aliphatic azides were captured intramolecularly by carbocations, producing aminodiazonium ion intermediates. Carbon-to-nitrogen rearrangement then occurred, generating bridged- or fused-bicyclic α-amino carbocations or iminium ions, depending on the geome
Stereoselectivity in the cyclisation of photoinduced electron transfer (PET) generated cyclic α -amino radicals: First general stereoselective entry to 1-azabicyclo (m:n:o) alkane systems
Pandey, Ganesh,Reddy, G. Devi
, p. 6533 - 6536 (2007/10/02)
Stereoselectivity in the intramolecular cyclisation of PET-generated cyclic α-amino radicals and its application to the synthesis of 1-azabicyclo (m:n:o) alkane systems is reported.
