909554-14-9Relevant articles and documents
Rhodium assisted C{single bond}H activation of N-(2′-hydroxyphenyl)benzaldimines. Synthesis, structure and electrochemical properties of a group of organorhodium complexes
Basu, Semanti,Dutta, Swati,Drew, Michael G.B.,Bhattacharya, Samaresh
, p. 3581 - 3588 (2007/10/03)
Reaction of a group of N-(2′-hydroxyphenyl)benzaldimines, derived from 2-aminophenol and five para-substituted benzaldehydes (the para substituents are OCH3, CH3, H, Cl and NO2), with [Rh(PPh3)3Cl] in refluxing toluene in the presence of a base (NEt3) afforded a family of organometallic complexes of rhodium(III). The crystal structure of one complex has been determined by X-ray crystallography. In these complexes the benzaldimine ligands are coordinated to the metal center, via dissociation of the phenolic proton and the phenyl proton at the ortho position of the phenyl ring in the imine fragment, as dianionic tridentate C,N,O-donors, and the two PPh3 ligands are trans. The complexes are diamagnetic (low-spin d6, S = 0) and show intense MLCT transitions in the visible region. Cyclic voltammetry shows a Rh(III){single bond}Rh(IV) oxidation within 0.63-0.93 V vs SCE followed by an oxidation of the coordinated benzaldimine ligand. A reduction of the coordinated benzaldimine is also observed within -0.96 to -1.04 V vs SCE. Potential of the Rh(III){single bond}Rh(IV) oxidation is found to be sensitive to the nature of the para-substituent.
