909911-54-2

Basic information

• Product Name: ethyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylseleno)cyclopent-3-ene-1-carboxylate
• Synonyms: ethyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylseleno)cyclopent-3-ene-1-carboxylate
• CAS NO: 909911-54-2
• Molecular Weight: 435.422
• Mol File: 909911-54-2.mol

Chemical Properties

• CAS DataBase Reference: ethyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylseleno)cyclopent-3-ene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylseleno)cyclopent-3-ene-1-carboxylate(909911-54-2)
• EPA Substance Registry System: ethyl (1S,2R)-2-[(2S)-1,4-dioxaspiro[4.5]dec-2-yl]-1-(phenylseleno)cyclopent-3-ene-1-carboxylate(909911-54-2)

Safety Data

• Hazardous Substances Data: 909911-54-2(Hazardous Substances Data)

Upstream product

• 727428-95-7 (3R,2'S)-(1',4'-dioxa-spiro[4.5]dec-2'-yl)-pent-4-enoic acid ethyl ester 
• 909911-31-5 ethyl (1R,2S)-2-[(2'S)-1',4'-dioxaspiro[4.5]dec-2'-yl]cyclopent-3-ene-1-carboxylate 
• 34837-55-3 Phenylselenyl bromide 

Relevant articles and documents

Stereodivergent approach to the asymmetric synthesis of bacillariolides: A formal synthesis of ent-bacillariolide II

Asymmetric synthesis of densely functionalized bicyclic frameworks for entry into bacillariolides I/III and ent-bacillariolide II is reported. The key features are ring-closing metathesis of a pair of diastereomerically related dienes obtained through a s