90999-53-4Relevant academic research and scientific papers
COMPLEXES OF THE TRIPOD LIGAND, TRIS(DIPHENYLPHOSPHINO)METHANE
Mague, Joel T.,Dessens, Steven E.
, p. 347 - 358 (2007/10/02)
Tris(diphenylphosphino)methane (TPM) is shown to exhibit a variety of coordination modes.In and it is monodentate while in and cis-, two of the three phosphorus atoms chelate to the metal.The uncoordinated arms of TPM in the mono- and bidentate complexes can coordinate other metals to give the homo- and heterobimetallic complexes , and trans-.In the last, an unusual virtually-coupled 31P NMR spectrum is seen.With (R=H, Cl) under mild conditions is formed in the ligand functions in a bidentate, bridging fashion while under more strenuous conditions the ligand-capped clusters form.
