910110-67-7Relevant academic research and scientific papers
Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2].
Cordero-Pensado, Viviana,Gómez-Benítez, Valente,Hernández-Ortega, Simón,Toscano, Rubén A.,Morales-Morales, David
, p. 4007 - 4018 (2008/10/09)
The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] has been examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. Analysis of these complexes by different spectroscopic techniques and single crystal X-ray diffraction studies revealed the formulations to be dependent of the stoichiometry and relative size of the metal center and thiolate. Analogous reactions with nickel complexes afforded oxidation decomposition products.
