91021-34-0Relevant academic research and scientific papers
REDUCTIVE FORMATION OF PYRIMIDINYLMETHYLENEPHOSPHORANES BY REACTION OF TRICHLOROMETHYLPYRIMIDINES WITH TRIPHENYLPHOSPHINE
Konno, Shoetsu,Sato, Yumi,Sakamoto, Takao,Katagiri, Nobuya,Yamanaka, Hiroshi
, p. 1331 - 1334 (2007/10/02)
The reaction of trichloromethylpyrimidines (1) with ca. 5 equivalent amounts of TPP gave pyrimidinylmethylenephosphoranes (9), whereas in the presence of 2 equivalent amounts of TPP, 1 was converted into the corresponding pyrimidinylchloromethylenephospho
