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[(C6H5C(O)N(CH(CH3)2)2)((CH3)2NCH2CH2N(CH3)CH2)Li(C6H4C(O)N(CH(CH3)2)2)Al(C4H9)2] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

910212-45-2

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910212-45-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 910212-45-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,1,0,2,1 and 2 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 910212-45:
(8*9)+(7*1)+(6*0)+(5*2)+(4*1)+(3*2)+(2*4)+(1*5)=112
112 % 10 = 2
So 910212-45-2 is a valid CAS Registry Number.

910212-45-2Downstream Products

910212-45-2Relevant academic research and scientific papers

New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide

Garcia-Alvarez, Joaquin,Graham, David V.,Kennedy, Alan R.,Mulvey, Robert E.,Weatherstone, Susan

, p. 3208 - 3210 (2006)

The first reported sodium alkyl(TMP)aluminate reagent to be synthesised and crystallographically characterised, [TMEDA·Na(μ-TMP)(μ- iBu)Al(iBu)2], reacts as an amido base towards phenylacetylene to form crystalline [(TMEDA)2·Na(μ-CCPh) (μ-iBu)Al(iBu)2]; whereas the congeneric TMEDA-stabilised lithium (TMP)aluminate exhibits dual alkyl/amido basicity in its reaction with N,N-diisopropylbenzamide to form a novel heterobimetallic- heterotrianionic crystalline complex [{PhC(=O)N(iPr) 2}·Li{2-[1-C(=O)N(iPr)2]C 6H4}{Me2NCH2CH2N(Me) CH2}Al(iBu)2], which, in addition to having an ortho-deprotonated benzamide ligand, also contains a methyl-deprotonated TMEDA ligand and a neutral benzamide molecule ligated to lithium. The Royal Society of Chemistry 2006.

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