910484-40-1

Upstream product

• 910484-38-7 (S)-4-[(5R,6S)-6-((E)-2-Benzenesulfonyl-propenyl)-5-isopropyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-benzyloxy-2-methyl-butyric acid methyl ester 
• 910484-44-5 (S)-2-Benzyloxy-4-[(5S,6R)-5-isopropenyl-6-methoxymethoxymethyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-methyl-butyric acid 
• 910484-36-5 (S)-2-Benzyloxy-4-[(5S,6R)-5-isopropenyl-6-methoxymethoxymethyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-methyl-butyric acid methyl ester 
• 910484-45-6 (S)-2-Benzyloxy-4-[(5R,6R)-5-isopropyl-6-methoxymethoxymethyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-methyl-butyric acid methyl ester 
• 910484-37-6 (S)-2-Benzyloxy-4-[(5R,6R)-6-hydroxymethyl-5-isopropyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-methyl-butyric acid methyl ester 
• 910484-46-7 (S)-2-Benzyloxy-4-[(5R,6R)-6-formyl-5-isopropyl-2-methyl-cyclohex-2-en-(E)-ylidene]-2-methyl-butyric acid methyl ester 
• 910484-39-8 (S)-4-[(2R,3S,5R,6S)-6-((E)-2-Benzenesulfonyl-propenyl)-2,3-dihydroxy-5-isopropyl-2-methyl-cyclohex-(E)-ylidene]-2-benzyloxy-2-methyl-butyric acid methyl ester 

Downstream Products

• 910484-42-3 (S)-3-[(1R,3R,3aR,4R)-3-((S)-1-Benzenesulfonyl-ethyl)-4-isopropyl-7-methyl-6-oxo-1,3,3a,4,5,6-hexahydro-isobenzofuran-1-yl]-2-benzyloxy-2-methyl-propionic acid methyl ester 
• 910484-41-2 (2S,4R)-4-[(5R,6S)-6-((E)-2-Benzenesulfonyl-propenyl)-5-isopropyl-2-methyl-3-oxo-cyclohex-1-enyl]-2-benzyloxy-4-hydroxy-2-methyl-butyric acid methyl ester 

Relevant academic research and scientific papers

Approach to the synthesis of cladiell-11-ene-3,6,7-triol

The synthesis of an advanced intermediate in the synthesis of the title compound has been achieved. Key steps include an Ireland-Claisen rearrangement to install the C7 tertiary alcohol stereocenter, an SN2′ reaction of an alkoxymethyl Cu reage