91055-83-3

Basic information

• Product Name: 2-(but-3-en-1-yl)cyclohex-2-en-1-ol
• Synonyms: 2-(but-3-en-1-yl)cyclohex-2-en-1-ol
• CAS NO: 91055-83-3
• Molecular Weight: 152.236
• Mol File: 91055-83-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(but-3-en-1-yl)cyclohex-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(but-3-en-1-yl)cyclohex-2-en-1-ol(91055-83-3)
• EPA Substance Registry System: 2-(but-3-en-1-yl)cyclohex-2-en-1-ol(91055-83-3)

Safety Data

• Hazardous Substances Data: 91055-83-3(Hazardous Substances Data)

Upstream product

• 78707-65-0 2-(but-3-en-1-yl)cyclohex-2-en-1-one 
• 23740-37-6 2-methoxycyclohex-2-en-1-one 
• 504-02-9 1,3-cylohexanedione 
• 56459-16-6 2-(but-3-en-1-yl)cyclohexane-1,3-dione 

Relevant articles and documents

Electrocatalytic generation of amidyl radicals for olefin hydroamidation: Use of solvent effects to enable anilide oxidation

Oxidative generation of synthetically important amidyl radicals from N-H amides is an appealing and yet challenging task. Previous methods require a stoichiometric amount of a strong oxidant and/or a costly noble-metal catalyst. We report herein the first electrocatalytic method that employs ferrocene (Fc), a cheap organometallic reagent, as the redox catalyst to produce amidyl radicals from N-aryl amides. Based on this radical-generating method, an efficient intramolecular olefin hydroamidation reaction has been developed. Easy access to N-arylamidyl radicals: The first electrocatalytic method for the generation of amidyl radicals from anilides has been developed using ferrocene (Cp2Fe) as a highly reactive, yet chemoselective redox catalyst. Based on this radical-generating method, a highly chemo- and diastereoselective olefin hydroamidation reaction has been developed.