910558-54-2Relevant academic research and scientific papers
Total synthesis of (-)- and enf-(+)-vindorosine: Tandem intramolecular -diels-alder/1,3-dipolar cycloaddition of 1,3,4-oxadiazoles
Elliott, Gregory I.,Velcicky, Juraj,Ishikawa, Hayato,Li, YongKai,Boger, Dale L.
, p. 620 - 622 (2006)
(Chemical Equation Presented) From tandem to pentacycle: The intramolecular tandem [4+2]/[3+2] cycloaddicycloaddition cascade of 1,3,4-oxadiazole (Z)-1 to give the pentacyclic skeleton 2 of (-)- and ent-(+)-vindorosine introduces all the requisite substituents and functionality in a single step by which three new rings and four C-C bonds form and all six key stereocenters are installed.
