91059-43-7

Usage

Chemical structure

Naphthalene core with iodine at position 1 and carboxylic acid at position 2.

Derivative of naphthalene

Modified version of the parent compound naphthalene.

Carboxylic acid functional group

Presence of -COOH group in the molecule.

Iodine substituent

An iodine atom attached to the naphthalene ring at position 1.

Building block in organic synthesis

Used as a starting material for creating other organic compounds.

Potential use in chemical reactions

Possesses reactivity that allows it to participate in various chemical processes.

Precursor for synthesis of other organic compounds

Acts as an intermediate in the production of other molecules.

Valuable tool for material and pharmaceutical development

Contributes to the creation of new substances in material science and drug discovery.

Reagent in research laboratories

Utilized in different chemical reactions for experimental purposes.

Upstream product

• 4919-43-1 1-amino-2-naphthoic acid 
• 91-57-6 2-Methylnaphthalene 
• 213991-84-5 1-iodo-2-hydroxymethylnaphtalene 
• 76635-70-6 (1-bromo-2-naphthyl)methanol 
• 364064-68-6 1-iodo-2-naphthalenecarboxaldehyde 

Downstream Products

• 1628347-91-0 C₁₇H₁₁ClINO 
• 1628347-75-0 8-(2-chlorophenyl)-8,13-dihydro-7H-benzo[b]naphtho-[1,2-e][1,4]diazepin-7-one 
• 1428865-20-6 C₁₉H₁₇NO₂ 
• 1428865-32-0 C₁₈H₁₇NO 
• 1428865-47-7 C₁₈H₁₅NO 

Relevant academic research and scientific papers

Catalytic enantioselective α-tosyloxylation of ketones using iodoaryloxazoline catalysts: Insights on the stereoinduction process

A family of iodooxazoline catalysts was developed to promote the iodine(III)-mediated α-tosyloxylation of ketone derivatives. The α-tosyloxy ketones produced are polyvalent chiral synthons. Through this study, we have unearthed a unique mode of stereoinduction from the chiral oxazoline moiety, where the stereogenic center alpha to the oxazoline oxygen atom is significant. Computational chemistry was used to rationalize the stereoinduction process. The catalysts presented promote currently among the best levels of activity and selectivity for this transformation. Evaluation of the scope of the reaction is presented.

Facile synthesis of C2-symmetric chiral binaphthyl ketone catalysts

C2-Symmetric chiral binaphthyl ketones, efficient catalysts for asymmetric epoxidation, have been synthesized through an intramolecular Ullmann reaction and/or a lipase-catalyzed enantioselective hydrolysis of the 11-membered cyclic binaphthyl acetate. (C) 2000 Elsevier Science Ltd.

Iodosonaphthoate catalysts for the cleavage of a reactive phosphate

Iodosonaphthoates 3-5 are potent catalysts for the hydrolysis of P-nitro-phenyldiphenyl phosphate.