91075-96-6Relevant academic research and scientific papers
Copper Nanoparticle Catalyzed Formation of C-S Bonds through Activation of S-S and C-H Bonds: An Easy Route to Alkynyl Sulfides
Mohan, Balaji,Hwang, Sori,Woo, Hyunje,Park, Kang Hyun
, p. 3741 - 3745 (2015/11/28)
An efficient method for copper nanoparticle catalyzed ligand-free S-Csp bond formation was developed by using dimethyl sulfoxide as the solvent, a base, and molecular oxygen as a green oxidant. This study provides a new catalytic route for the
Cu(i)-catalyzed aerobic cross-dehydrogenative coupling of terminal alkynes with thiols for the construction of alkynyl sulfides
Yang, Yong,Dong, Weibing,Guo, Yisong,Rioux, Robert M.
supporting information, p. 3170 - 3175 (2013/11/06)
Highly active and selective aerobic cross-dehydrogenative coupling of terminal alkynes with thiols to construct alkynyl sulfides catalyzed by Cu(i) using molecular oxygen as the oxidant has been demonstrated under mild reaction conditions. The process is applicable to a wide range of alkynes and various thiols and is compatible with a variety of functional groups on both alkyne and thiol coupling partners.
Electrophile induced rearrangement of 1-alkynylaluminium ate complexes
Debuigne, Antoine,Gerard, Julien,Hevesi, Laszlo
, p. 5943 - 5944 (2007/10/03)
The title species have been shown to rearrange under the influence of the electrophile PhSCl to give tetrasubstituted vinylaluminium compounds protonolysis of which led to the corresponding vinyl sulfides in a highly stereoselective manner.
Convenient preparation of alkynyl selenides, sulfides and tellurides from terminal alkynes and phenylchalcogenyl halides in the presence of copper(I) iodide
Braga,Silveira,Reckziegel,Menezes
, p. 8041 - 8042 (2007/10/02)
Alkynyl selenides, sulfides and tellurides were obtained under very mild conditions by reacting terminal alkynes with phenylchalcogenyl halides in the presence of copper iodide(I).
PYROLYSIS OF α-ACYL,α-THIO PHOSPHORANES THIOACETYLENES
Braga, Antonio L.,Comasseto, Joao V.,Petragnani, Nicola
, p. 1111 - 1114 (2007/10/02)
Pyrolysis of α-acyl,α-thio phosphoranes affords thioacetylenes in a good yield.The thio acethylenes are precursors of terminal and alkyl disubstituted acetylenes.
