91078-39-6

Upstream product

• 186581-53-3 diazomethane 
• 67991-38-2 mortonin C 

Downstream Products

• 91078-44-3 (2R,3R,3aS,4S,7S,7aR)-3,4-Bis-benzoyloxy-7-hydroxy-3a,7-dimethyl-hexahydro-benzofuran-2,7a-dicarboxylic acid dimethyl ester 
• 91078-45-4 (2R,3R,3aS,4S,7S,7aR)-3,4-Bis-benzoyloxy-7-hydroxy-3a,7-dimethyl-hexahydro-benzofuran-2,7a-dicarboxylic acid 7a-methyl ester 
• 91078-42-1 (1S,4S,7S,8S,9R)-7,11-Bis-benzoyloxy-4,8-dimethyl-2-oxo-3,10-dioxa-tricyclo[6.2.1.0^4,9]undecane-9-carboxylic acid methyl ester 
• 91078-40-9 (2S,3aS,4S,7S,7aR)-3,4-Bis-benzoyloxy-7-hydroxy-2-isobutyl-3a,7-dimethyl-hexahydro-benzofuran-7a-carboxylic acid methyl ester 
• 91078-43-2 (2R,3aS,4S,7S,7aR)-3,4-Bis-benzoyloxy-2-formyl-7-hydroxy-3a,7-dimethyl-hexahydro-benzofuran-7a-carboxylic acid methyl ester 
• 91078-40-9 (2R,3R,3aS,4S,7aR)-3,4-Bis-benzoyloxy-7-hydroxy-2-isobutyl-3a,7-dimethyl-hexahydro-benzofuran-7a-carboxylic acid methyl ester 
• 91078-41-0 (1S,4S,7S,8S,9R)-7,11-Bis-benzoyloxy-2-hydroxy-4,8-dimethyl-3,10-dioxa-tricyclo[6.2.1.0^4,9]undecane-9-carboxylic acid methyl ester 

Relevant academic research and scientific papers

PHOTOCHEMICAL REARRANGEMENT OF MORTONIN C

Irradiation of Mortonin C (1a) produced the photoproducts 4a and 8a as a result of a photochemically induced ring contraction of the tetrahydro-oxepine nucleus.Te structure and stereochemistry of 4a and 8a were proved by chemical degradation and spectrosc