911047-11-5Relevant academic research and scientific papers
Preparation and decarboxylative rearrangement of (Z)-enyne esters
Woo, Jacqueline C.S.,Walker, Shawn D.,Faul, Margaret M.
, p. 5679 - 5682 (2007)
A method to assemble (Z)-enyne esters via palladium-catalyzed cross coupling reactions of enol tosylates is reported. A base-mediated one-pot decarboxylative rearrangement of the enynes to enones is described. The scope of this process is examined.
Palladium-Catalyzed One-Pot Highly Regioselective 6- Endo Cyclization and Alkylation of Enynoates: Synthesis of 2-Alkanone Pyrones
Ahmad, Tanveer,Qiu, Sheng-Qi,Xu, Yun-He,Loh, Teck-Peng
, p. 13414 - 13426 (2018/11/02)
The Pd(II)-catalyzed one-pot tandem cyclization/alkylation reactions of enynoates with allylic alcohols have been demonstrated. In this reaction, an innovative protocol proceeded well through Pd-catalyzed intramolecular selective 6-endo cyclization, inser
Palladium-catalyzed alkoxycarbonylation of (Z)-2-en-4-yn carbonates leading to 2,3,5-trienoates
Akpinar, G. Eray,Kus, Melih,Uecuencue, Muhammed,Karakus, Erman,Artok, Levent
supporting information; experimental part, p. 748 - 751 (2011/04/24)
Pd(0)-catalyzed carbonylation of (Z)-2-en-4-yn carbonates in the presence of a balloon pressure of CO in an alcohol donates vinylallenyl esters with an exclusively E-configuration and in high yields. The fact that no such reactivity could be observed with
