91106-44-4Relevant academic research and scientific papers
Dehydrogenation with Benzeneseleninic Anhydride in the Total Synthesis of Ergot Alkaloids
Ninomiya, Ichiya,Hashimoto, Chiyomi,Kiguchi, Toshiko,Naito, Takeaki,Barton, Derek, H. R.,et al.
, p. 707 - 713 (2007/10/02)
Investigation of the dehydrogenative conversion of indolines into indoles with benzeneseleninic anhydride (1) resulted in the development of an efficient standardised procedure, which was successfully applied to the final steps in first total synthesis of (+/-)-lysergol (18), (+/-)-isolysergol (27), and (+/-)-elymoclavine (29).
TOTAL SYNTHESIS OF ERGOT ALKALOIDS, (+/-)-ELYMOCLAVINE AND (+/-)-ISOLYSERGOL
Ninomiya, Ichiya,Hashimoto, Chiyomi,Kiguchi, Toshiko
, p. 1035 - 1038 (2007/10/02)
Two of the hitherto untouched ergot alkaloids, (+/-)-elymoclavine and (+/-)-isolysergol, were synthesized according to the synthetic route involving enamide photocyclization.
